I imagine their conversations are going more like: "Why does Steve get to kill her? I'm such a better shot." "Cuz Steve pulled rank. Besides you wanna be the one shooting if she dodges the blast and turns around?" "Meh good point. Man, he's living the dream though. How many people can say they got to legally assasinate their boss." "I hear ya."
Nope she's their Commander, or at least she was until Order 66. Now she's target practice.
:ahem: Anyway she dodges that first shot her Captain makes but like you said he has an army. She didn't have much of a chance.